Witryna21 paź 2024 · Request PDF Palladium(II) complexes bearing 1-iminothiolate-3,5-dimethylpyrazoles: synthesis, cytotoxicity, DNA binding and enzymatic inhibition … WitrynaSNS platinum(II) pincer complexes reversibly bind and release the surrogate half sulfur mustard, 2-chloroethyl ethyl sulfide (CEES). The switch-like behavior of the pincers is …
Tetra- and hexanuclear copper(I) iminothiolate complexes: …
Witryna1 kwi 1995 · Mechanistic study of CO/CO 2 conversion catalyzed by a biomimetic Ni(II)-iminothiolate complex. International Journal of Quantum Chemistry 2024 , 118 (9) , e25555. Witryna11 cze 2024 · However, the number of examples of thioamide-based metal clusters is limited. A thioamide group is one of the sulfur-based donating groups for constructing organometallic compounds [5,6] . Upon deprotonation, a secondary thioamide group forms thioamidate and iminothiolate as resonance structures ( Scheme 1 ). diabetic low carb diet plan printable
A Novel Tridentate-N,N,S Iminothiolate Ligand That Leads to the ...
WitrynaTreatment of dicyandiamide, 2-aminoethanethiol hydrochloride, and NiCl2·6H2O in water gave an S-bridged dinickel(II) complex, [Ni2(L)2]Cl2 ([1]Cl2), which contains novel tridentate-N,N,S iminothiolate ligands with a biguanide moiety (L−). Another S-bridged complex containing L−, [Co{Co(L)2}3]6+ ([2]Cl6), which has the first example of a … WitrynaPalladium( ii ) complexes bearing 1-iminothiolate-3,5-dimethylpyrazoles: synthesis, cytotoxicity, DNA binding and enzymatic inhibition studies. New Journal of Chemistry 2024 , 44 (45) , 19891-19901. Witryna30 gru 2011 · The on−off switch is a result of the reversible transformation between thioamide (unreactive) and iminothiolate (reactive) forms of the pincer skeleton … cindy veenhof umcu